NickelMaghrebV1, Main, Exploration, bibRecord, 000F05

Synthesis of new functionalized polyenes by cooligomerization of butadiene with methyl acrylate on nickel catalysts

Identifieur interne : 000F05 ( Main/Exploration ); précédent : 000F04; suivant : 000F06

Synthesis of new functionalized polyenes by cooligomerization of butadiene with methyl acrylate on nickel catalysts

Auteurs : A. Elamrani [Maroc] ; I. Suisse [France] ; A. Mortreux [France] ; N. Knouzi [Maroc]

Source :

Journal of Molecular Catalysis A: Chemical [ 1381-1169 ] ; 1995.

RBID : ISTEX:4A745325008BCD53111D9D16FE86D7FDFD8B287D

Descripteurs français

Pascal (Inist)
- Acrylate de méthyle copolymère, Activité catalytique, Butadiène copolymère, Composé polyénique, Cooligomère, Cooligomérisation, Copolymère insaturé, Etude expérimentale, Mécanisme réaction, Nickel complexe, Oligomérisation catalyseur complexe, Phosphine tertiaire, Phosphite organique, Préparation, Sélectivité catalyseur, Transfert proton.

English descriptors

KwdEn :
- Butadiene copolymer, Catalyst activity, Catalyst selectivity, Complex catalyst oligomerization, Cooligomer, Cooligomerization, Experimental study, Methyl acrylate copolymer, Nickel complex, Organic phosphite, Polyenic compound, Preparation, Proton transfer, Reaction mechanism, Tertiary phosphine, Unsaturated copolymer.

Abstract

New polyenes are formed in protic media via nickel catalyzed cooligomerization of butadiene with methyl acrylate. High activities are achieved with amino-phosphinite ligands in aprotic solvent. Using a deuterium labeled ligand, the presence of the NH group of the ligand is shown to be the key point for the proton transfer involved in the mechanism.

Url:

https://api.istex.fr/document/4A745325008BCD53111D9D16FE86D7FDFD8B287D/fulltext/pdf

DOI: 10.1016/1381-1169(95)00085-2

Affiliations:

Le document en format XML

<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title>Synthesis of new functionalized polyenes by cooligomerization of butadiene with methyl acrylate on nickel catalysts</title>
<author><name sortKey="Elamrani, A" sort="Elamrani, A" uniqKey="Elamrani A" first="A." last="Elamrani">A. Elamrani</name>
</author>
<author><name sortKey="Suisse, I" sort="Suisse, I" uniqKey="Suisse I" first="I." last="Suisse">I. Suisse</name>
</author>
<author><name sortKey="Mortreux, A" sort="Mortreux, A" uniqKey="Mortreux A" first="A." last="Mortreux">A. Mortreux</name>
</author>
<author><name sortKey="Knouzi, N" sort="Knouzi, N" uniqKey="Knouzi N" first="N." last="Knouzi">N. Knouzi</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:4A745325008BCD53111D9D16FE86D7FDFD8B287D</idno>
<date when="1995" year="1995">1995</date>
<idno type="doi">10.1016/1381-1169(95)00085-2</idno>
<idno type="url">https://api.istex.fr/document/4A745325008BCD53111D9D16FE86D7FDFD8B287D/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">000487</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000487</idno>
<idno type="wicri:Area/Istex/Curation">000231</idno>
<idno type="wicri:Area/Istex/Checkpoint">000839</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000839</idno>
<idno type="wicri:doubleKey">1381-1169:1995:Elamrani A:synthesis:of:new</idno>
<idno type="wicri:Area/Main/Merge">000F62</idno>
<idno type="wicri:source">INIST</idno>
<idno type="RBID">Pascal:95-0496912</idno>
<idno type="wicri:Area/PascalFrancis/Corpus">000551</idno>
<idno type="wicri:Area/PascalFrancis/Curation">000516</idno>
<idno type="wicri:Area/PascalFrancis/Checkpoint">000546</idno>
<idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000546</idno>
<idno type="wicri:doubleKey">1381-1169:1995:Elamrani A:synthesis:of:new</idno>
<idno type="wicri:Area/Main/Merge">001017</idno>
<idno type="wicri:Area/Main/Curation">000F05</idno>
<idno type="wicri:Area/Main/Exploration">000F05</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a">Synthesis of new functionalized polyenes by cooligomerization of butadiene with methyl acrylate on nickel catalysts</title>
<author><name sortKey="Elamrani, A" sort="Elamrani, A" uniqKey="Elamrani A" first="A." last="Elamrani">A. Elamrani</name>
<affiliation wicri:level="1"><country xml:lang="fr">Maroc</country>
<wicri:regionArea>Université C. Doukali, Faculté des Sciences, Département Chimie, BP 20, El Jadida</wicri:regionArea>
<wicri:noRegion>El Jadida</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Suisse, I" sort="Suisse, I" uniqKey="Suisse I" first="I." last="Suisse">I. Suisse</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire de Catalyse Hétérogène et Homogène, Groupe de Chimie Organique Appliquée, USTL, ENSCL, URA CNRS 402, BP 108, 59652 Villeneuve d'Ascq</wicri:regionArea>
<placeName><region type="region" nuts="2">Hauts-de-France</region>
<region type="old region" nuts="2">Nord-Pas-de-Calais</region>
<settlement type="city">Villeneuve d'Ascq</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Mortreux, A" sort="Mortreux, A" uniqKey="Mortreux A" first="A." last="Mortreux">A. Mortreux</name>
<affiliation></affiliation>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire de Catalyse Hétérogène et Homogène, Groupe de Chimie Organique Appliquée, USTL, ENSCL, URA CNRS 402, BP 108, 59652 Villeneuve d'Ascq</wicri:regionArea>
<placeName><region type="region" nuts="2">Hauts-de-France</region>
<region type="old region" nuts="2">Nord-Pas-de-Calais</region>
<settlement type="city">Villeneuve d'Ascq</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Knouzi, N" sort="Knouzi, N" uniqKey="Knouzi N" first="N." last="Knouzi">N. Knouzi</name>
<affiliation wicri:level="1"><country xml:lang="fr">Maroc</country>
<wicri:regionArea>Université C. Doukali, Faculté des Sciences, Département Chimie, BP 20, El Jadida</wicri:regionArea>
<wicri:noRegion>El Jadida</wicri:noRegion>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j">Journal of Molecular Catalysis A: Chemical</title>
<title level="j" type="abbrev">MOLCAA</title>
<idno type="ISSN">1381-1169</idno>
<imprint><publisher>ELSEVIER</publisher>
<date type="published" when="1995">1995</date>
<biblScope unit="volume">101</biblScope>
<biblScope unit="issue">3</biblScope>
<biblScope unit="page" from="211">211</biblScope>
<biblScope unit="page" to="215">215</biblScope>
</imprint>
<idno type="ISSN">1381-1169</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">1381-1169</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Butadiene copolymer</term>
<term>Catalyst activity</term>
<term>Catalyst selectivity</term>
<term>Complex catalyst oligomerization</term>
<term>Cooligomer</term>
<term>Cooligomerization</term>
<term>Experimental study</term>
<term>Methyl acrylate copolymer</term>
<term>Nickel complex</term>
<term>Organic phosphite</term>
<term>Polyenic compound</term>
<term>Preparation</term>
<term>Proton transfer</term>
<term>Reaction mechanism</term>
<term>Tertiary phosphine</term>
<term>Unsaturated copolymer</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Acrylate de méthyle copolymère</term>
<term>Activité catalytique</term>
<term>Butadiène copolymère</term>
<term>Composé polyénique</term>
<term>Cooligomère</term>
<term>Cooligomérisation</term>
<term>Copolymère insaturé</term>
<term>Etude expérimentale</term>
<term>Mécanisme réaction</term>
<term>Nickel complexe</term>
<term>Oligomérisation catalyseur complexe</term>
<term>Phosphine tertiaire</term>
<term>Phosphite organique</term>
<term>Préparation</term>
<term>Sélectivité catalyseur</term>
<term>Transfert proton</term>
</keywords>
</textClass>
<langUsage><language ident="en">en</language>
</langUsage>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">New polyenes are formed in protic media via nickel catalyzed cooligomerization of butadiene with methyl acrylate. High activities are achieved with amino-phosphinite ligands in aprotic solvent. Using a deuterium labeled ligand, the presence of the NH group of the ligand is shown to be the key point for the proton transfer involved in the mechanism.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
<li>Maroc</li>
</country>
<region><li>Hauts-de-France</li>
<li>Nord-Pas-de-Calais</li>
</region>
<settlement><li>Villeneuve d'Ascq</li>
</settlement>
</list>
<tree><country name="Maroc"><noRegion><name sortKey="Elamrani, A" sort="Elamrani, A" uniqKey="Elamrani A" first="A." last="Elamrani">A. Elamrani</name>
</noRegion>
<name sortKey="Knouzi, N" sort="Knouzi, N" uniqKey="Knouzi N" first="N." last="Knouzi">N. Knouzi</name>
</country>
<country name="France"><region name="Hauts-de-France"><name sortKey="Suisse, I" sort="Suisse, I" uniqKey="Suisse I" first="I." last="Suisse">I. Suisse</name>
</region>
<name sortKey="Mortreux, A" sort="Mortreux, A" uniqKey="Mortreux A" first="A." last="Mortreux">A. Mortreux</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/NickelMaghrebV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000F05 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000F05 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    NickelMaghrebV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     ISTEX:4A745325008BCD53111D9D16FE86D7FDFD8B287D
   |texte=   Synthesis of new functionalized polyenes by cooligomerization of butadiene with methyl acrylate on nickel catalysts
}}

This area was generated with Dilib version V0.6.27.
Data generation: Fri Mar 24 23:14:20 2017. Site generation: Tue Mar 5 17:03:47 2024

Serveur d'exploration sur le nickel au Maghreb

Synthesis of new functionalized polyenes by cooligomerization of butadiene with methyl acrylate on nickel catalysts

Synthesis of new functionalized polyenes by cooligomerization of butadiene with methyl acrylate on nickel catalysts

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

	Serveur d'exploration sur le nickel au Maghreb
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.